JAMB 2012 Chemistry · Question 29

Mineral acids are usually added to commercial hydrogen peroxide to

Options

  1. A.oxidize it
  2. B.decompose it
  3. C.minimize its decomposition
  4. D.reduce it to water and oxygen

Answer: C. minimize its decomposition

Explanation written with AI and checked against the answer key

Analyze the question: Why do manufacturers add mineral acids (such as dilute H₂SO₄ or H₃PO₄) to commercial hydrogen peroxide?

Concept: Hydrogen peroxide is unstable and tends to decompose into water and oxygen:

2H₂O₂ → 2H₂O + O₂

This decomposition is catalysed by several things:

  • Light
  • Heat
  • Traces of alkali
  • Metal ions and impurities (e.g. Fe³⁺, Mn²⁺) and rough surfaces

H₂O₂ is more stable in slightly acidic conditions. Alkaline conditions speed up its breakdown. So manufacturers:

  • Store it in dark or opaque bottles (to keep out light)
  • Add a small amount of mineral acid, and sometimes stabilisers such as phosphoric acid, to keep the solution slightly acidic and slow the decomposition.

Solution, going through the options:

  • A. Oxidize it: Wrong. Acid is not added to oxidize H₂O₂, and doing so would not be useful.
  • B. Decompose it: Wrong. This is the opposite of the purpose, since manufacturers want it to last.
  • C. Minimize its decomposition: Correct. The acid makes the solution slightly acidic and counters traces of alkali, which stabilises the peroxide and slows its breakdown.
  • D. Reduce it to water and oxygen: Wrong. This is just the decomposition reaction, which the acid is meant to prevent.

Answer: C. Minimize its decomposition

Exam tip: Remember "H₂O₂ is happy in acid, unhappy in alkali, light and heat." Whenever you see a question on storing or stabilising H₂O₂, think: dark bottle, cool place, a little acid. Any option about speeding up decomposition is a distractor.

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