JAMB 2012 Chemistry · Question 29
Mineral acids are usually added to commercial hydrogen peroxide to
Options
- A.oxidize it
- B.decompose it
- C.minimize its decomposition
- D.reduce it to water and oxygen
Answer: C. minimize its decomposition
Explanation written with AI and checked against the answer key
Analyze the question: Why do manufacturers add mineral acids (such as dilute H₂SO₄ or H₃PO₄) to commercial hydrogen peroxide?
Concept: Hydrogen peroxide is unstable and tends to decompose into water and oxygen:
2H₂O₂ → 2H₂O + O₂
This decomposition is catalysed by several things:
- Light
- Heat
- Traces of alkali
- Metal ions and impurities (e.g. Fe³⁺, Mn²⁺) and rough surfaces
H₂O₂ is more stable in slightly acidic conditions. Alkaline conditions speed up its breakdown. So manufacturers:
- Store it in dark or opaque bottles (to keep out light)
- Add a small amount of mineral acid, and sometimes stabilisers such as phosphoric acid, to keep the solution slightly acidic and slow the decomposition.
Solution, going through the options:
- A. Oxidize it: Wrong. Acid is not added to oxidize H₂O₂, and doing so would not be useful.
- B. Decompose it: Wrong. This is the opposite of the purpose, since manufacturers want it to last.
- C. Minimize its decomposition: Correct. The acid makes the solution slightly acidic and counters traces of alkali, which stabilises the peroxide and slows its breakdown.
- D. Reduce it to water and oxygen: Wrong. This is just the decomposition reaction, which the acid is meant to prevent.
Answer: C. Minimize its decomposition
Exam tip: Remember "H₂O₂ is happy in acid, unhappy in alkali, light and heat." Whenever you see a question on storing or stabilising H₂O₂, think: dark bottle, cool place, a little acid. Any option about speeding up decomposition is a distractor.
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