JAMB 2012 Chemistry · Question 13
An increase in the pressure exerted on gas at a constant temperature results in
Options
- A.a decrease in the number of effective collisions
- B.a decrease in volume
- C.an increase in the average intermolecular distance
- D.an increase in volume
Answer: B. a decrease in volume
Explanation written with AI and checked against the answer key
Analysis
The question asks for the effect of increasing pressure on a gas when the temperature is kept constant. This is a classic application of the Gas Laws, specifically Boyle's Law.
Concept: Boyle's Law
Boyle's Law states that for a fixed mass of an ideal gas at a constant temperature, the pressure () of the gas is inversely proportional to its volume ().
Mathematically, this is expressed as:
Where:
- = Pressure
- = Volume
- = Constant
This means that if you increase the pressure on a gas, the particles are forced closer together, which causes the volume to decrease. Conversely, if you decrease the pressure, the volume increases.
Step-by-Step Solution
- Identify the variables: We are dealing with Pressure () and Volume () at a constant Temperature ().
- Apply the relationship: According to Boyle's Law, and have an inverse relationship.
- Analyze the change: The question states that pressure is increased.
- Determine the result: Because the relationship is inverse, an increase in pressure must lead to a decrease in volume.
- Evaluate the options: • A: Incorrect. Increasing pressure actually increases the frequency of collisions because particles are closer together. • B: Correct. This aligns with Boyle's Law. • C: Incorrect. Increasing pressure forces particles closer together, so the intermolecular distance decreases, not increases. • D: Incorrect. This describes a decrease in pressure, not an increase.
Conclusion
When you compress a gas (increase pressure) at a constant temperature, the gas molecules occupy a smaller space, resulting in a decrease in volume.
Exam Tip
Whenever you see a gas law question, remember the "P-V-T" rule:
- Boyle's Law: Temperature is constant ().
- Charles's Law: Pressure is constant ().
- Pressure Law: Volume is constant ().
- Memory Trick: Think of a balloon. If you squeeze it (increase pressure), it gets smaller (decrease volume).
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