JAMB 2012 Chemistry · Question 13

An increase in the pressure exerted on gas at a constant temperature results in

Options

  1. A.a decrease in the number of effective collisions
  2. B.a decrease in volume
  3. C.an increase in the average intermolecular distance
  4. D.an increase in volume

Answer: B. a decrease in volume

Explanation written with AI and checked against the answer key

Analysis

The question asks for the effect of increasing pressure on a gas when the temperature is kept constant. This is a classic application of the Gas Laws, specifically Boyle's Law.

Concept: Boyle's Law

Boyle's Law states that for a fixed mass of an ideal gas at a constant temperature, the pressure (PP) of the gas is inversely proportional to its volume (VV).

Mathematically, this is expressed as:

P∝1VorPV=kP \propto \frac{1}{V} \quad \text{or} \quad PV = k

Where:

  • PP = Pressure
  • VV = Volume
  • kk = Constant

This means that if you increase the pressure on a gas, the particles are forced closer together, which causes the volume to decrease. Conversely, if you decrease the pressure, the volume increases.

Step-by-Step Solution
  1. Identify the variables: We are dealing with Pressure (PP) and Volume (VV) at a constant Temperature (TT).
  2. Apply the relationship: According to Boyle's Law, PP and VV have an inverse relationship.
  3. Analyze the change: The question states that pressure is increased.
  4. Determine the result: Because the relationship is inverse, an increase in pressure must lead to a decrease in volume.
  5. Evaluate the options: • A: Incorrect. Increasing pressure actually increases the frequency of collisions because particles are closer together. • B: Correct. This aligns with Boyle's Law. • C: Incorrect. Increasing pressure forces particles closer together, so the intermolecular distance decreases, not increases. • D: Incorrect. This describes a decrease in pressure, not an increase.
Conclusion

When you compress a gas (increase pressure) at a constant temperature, the gas molecules occupy a smaller space, resulting in a decrease in volume.

Exam Tip

Whenever you see a gas law question, remember the "P-V-T" rule:

  • Boyle's Law: Temperature is constant (P∝1/VP \propto 1/V).
  • Charles's Law: Pressure is constant (V∝TV \propto T).
  • Pressure Law: Volume is constant (P∝TP \propto T).
  • Memory Trick: Think of a balloon. If you squeeze it (increase pressure), it gets smaller (decrease volume).

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