JAMB 2012 Chemistry · Question 43

A common characteristic between zinc and the other transition elements is the ability to

Options

  1. A.have variable oxidation states
  2. B.from complex ions
  3. C.act as a catalyst
  4. D.from coloured ions

Answer: B. from complex ions

Explanation written with AI and checked against the answer key

1. Analyze the question

The question asks for a property that zinc shares with other transition elements. To answer this, we must recall the definition of transition elements and the unique electronic configuration of zinc.

2. Explain the concept
  • Transition Elements: By definition, a transition element is an element that has an incomplete dd-subshell in its neutral state or in at least one of its common oxidation states.
  • Zinc (ZnZn): Zinc has an electronic configuration of [Ar]3d104s2[Ar] 3d^{10} 4s^2. Even in its common oxidation state (Zn2+Zn^{2+}), its configuration is [Ar]3d10[Ar] 3d^{10}. Because its dd-subshell is completely filled, zinc is technically not a transition element according to the strict IUPAC definition.
  • Comparison: • Variable oxidation states: Most transition metals exhibit multiple oxidation states (e.g., Fe2+,Fe3+Fe^{2+}, Fe^{3+}). Zinc only exhibits +2+2. • Coloured ions: Transition metals form coloured ions due to d−dd-d transitions. Because zinc has a full dd-subshell, it cannot undergo d−dd-d transitions, so its ions are colourless. • Catalytic activity: Transition metals act as catalysts due to their variable oxidation states and ability to provide surface area. Zinc is generally not considered a good catalyst compared to metals like Fe,Ni,Fe, Ni, or VV. • Complex ion formation: Both transition metals and zinc have the ability to form complex ions (coordination compounds) by donating lone pairs of electrons into empty orbitals (e.g., [Zn(NH3)4]2+[Zn(NH_3)_4]^{2+}).
3. Show the solution
  • Option A: Incorrect. Zinc only shows a +2+2 oxidation state.
  • Option C: Incorrect. Zinc does not possess the variable oxidation states required for typical transition metal catalysis.
  • Option D: Incorrect. Zinc ions (Zn2+Zn^{2+}) are colourless because the 3d3d subshell is full.
  • Option B: Correct. Despite not being a "true" transition metal, zinc shares the ability to form stable complex ions with transition metals because it has empty 4s4s and 4p4p orbitals available for coordinate bonding.
4. Identify the answer

The correct option is B.

5. Exam Tip

When you see a question about zinc in the context of transition metals, always remember the "Zinc Exception": Zinc is the "odd one out" because it lacks variable oxidation states, coloured ions, and catalytic properties. However, it behaves like a transition metal specifically in its ability to form complex ions.

AI can make mistakes. Report anything that looks wrong.

Past questions © the examination body (JAMB/WAEC/NECO). DeeepSolve is not affiliated with them. Rights holders: see /copyright.