JAMB 2011 Chemistry · Question 13

CH3COOH(aq) + OH-(aq) ↔ CH3COO-(aq) + H2O(l) In the reaction above ,CH3COO-(aq) is

Options

  1. A.conjugate base
  2. B.acid
  3. C.base
  4. D.conjugate acid

Answer: A. conjugate base

Explanation written with AI and checked against the answer key

Analysis

This question tests your understanding of the Brønsted-Lowry Theory of Acids and Bases. According to this theory, an acid is a proton (H+H^+) donor, and a base is a proton acceptor. When an acid loses a proton, it forms a conjugate base. When a base gains a proton, it forms a conjugate acid.

Concept Explanation

In any acid-base reaction, we look at the relationship between the reactants and the products:

  1. The Acid: CH3COOHCH_3COOH (ethanoic acid) donates a proton (H+H^+) to the OH−OH^- ion.
  2. The Base: OH−OH^- (hydroxide ion) accepts the proton.
  3. The Conjugate Base: After CH3COOHCH_3COOH loses its proton, it becomes CH3COO−CH_3COO^- (ethanoate ion). Because it is the species left behind after the acid has donated its proton, it is called the conjugate base.
  4. The Conjugate Acid: After OH−OH^- accepts the proton, it becomes H2OH_2O. Because it is the species formed after the base has accepted a proton, it is called the conjugate acid.
Step-by-Step Solution
  • Step 1: Identify the reactant that loses the proton. CH3COOH→CH3COO−+H+CH_3COOH \rightarrow CH_3COO^- + H^+. Since CH3COOHCH_3COOH is the acid, the resulting CH3COO−CH_3COO^- is its conjugate base.
  • Step 2: Identify the reactant that gains the proton. OH−+H+→H2OOH^- + H^+ \rightarrow H_2O. Since OH−OH^- is the base, the resulting H2OH_2O is its conjugate acid.
  • Step 3: Match the species in the question. The question asks for the identity of CH3COO−CH_3COO^-. Based on our analysis, it is the conjugate base of CH3COOHCH_3COOH.
Conclusion
Exam Tip

Remember the "minus one" rule: A conjugate base is always what remains of an acid after it has lost one H+H^+. If you are ever confused, just look at the pair: the one with one less hydrogen is the conjugate base!

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